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During the last decade, the chemistry of d0/fn actinides hasflourished reaching a high level of sophistication. Compared to the early or late transition-metalcomplexes and lanthanides, the actinides sometimes exhibit parallel but mostly complementary activitiesfor similar organic processes, and sometimes even challenge the activities of the transition...
The low-valent complexes of uranium (i.e. those containing U(III) centres) are characterisedas reactive, highly reducing species that can effect novel, and potentially useful, transformationsof small molecules. In this chapter we review one particular class of these compounds – thosesupported by cyclooctatetraene and pentalene ligands – whose reduction chemistry has recentlydemonstrated novel and...
The coordination chemistry of uranium has become an increasingly popular topic in the last 15 years.Much of the reason for this interest has come from the development of easy to synthesize, stable startingmaterials. These materials allowed an entry point for the exploration of uranium with any ligand imaginable.This chapter covers the most significant developments in the coordination chemistry of...
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